Factory Sells Best Quality O-TOLYL ACETATE 533-18-6 with ISO standards
- Molecular Formula: C9H10O2
- Molecular Weight: 150.177
- Refractive Index: 1.4980-1.5010
- Boiling Point: 207.2 °C at 760 mmHg
- Flash Point: 84 °C
- PSA： 26.30000
- Density: 1.047 g/cm3
- LogP: 1.92030
O-TOLYL ACETATE(Cas 533-18-6) Usage
|
Preparation |
From sodium o-cresol and acetic anhydride. |
InChI:InChI=1/C9H10O2/c1-7-5-3-4-6-9(7)11-8(2)10/h3-6H,1-2H3
533-18-6 Relevant articles
Submicron ZnO raspberries as effective catalysts for Fries rearrangement
Ali, Mohammed,Rahaman, Hasimur,Pal, Sudip Kumar,Kar, Nikita,Ghosh, Sujit Kumar
, p. 41780 - 41785 (2015)
o-Xylene-in-water emulsion droplets have...
Method for promoting acylation of amine or alcohol by carbon dioxide
-
Paragraph 0034-0035, (2021/05/29)
The invention relates to a method for pr...
An efficient method to prepare aryl acetates by the carbonylation of aryl methyl ethers or phenols
Zhang, Dejin,Yang, Guoqiang,Xiong, Junping,Liu, Jia,Hu, Xingbang,Zhang, Zhibing
, p. 2683 - 2687 (2021/02/16)
Synthesis of valuable chemicals from lig...
Steric effect of NHC ligands in Pd(II)–NHC-catalyzed non-directed C–H acetoxylation of simple arenes
Mandal, Tanmoy,Yadav, Sudha,Choudhury, Joyanta
, (2021/09/06)
Although there has been a lot of progres...
Synthetic method of benzofuranone
-
Paragraph 0066-0070, (2020/06/16)
The invention provides a synthetic metho...
533-18-6 Process route
-
-
10387-40-3
potassium thioacetate
-
-
108-95-2,27073-41-2
phenol
-
-
533-18-6
2-methylphenyl acetate
| Conditions | Yield |
|---|---|
|
With
carbon dioxide;
at 100 ℃;
for 14h;
under 760.051 Torr;
|
83%
|
-
-
108-24-7
acetic anhydride
-
-
95-48-7,77504-84-8
ortho-cresol
-
-
533-18-6
2-methylphenyl acetate
| Conditions | Yield |
|---|---|
|
at 20 ℃;
for 0.666667h;
|
100%
|
|
With
triethylamine;
In
dichloromethane;
at 20 ℃;
|
99%
|
|
With
silver trifluoromethanesulfonate;
at 60 ℃;
for 0.116667h;
neat (no solvent);
|
99%
|
|
With
magnesium;
In
neat (no solvent);
at 25 ℃;
for 18h;
Temperature;
|
98%
|
|
With
lithium bis(perfluorooctylsulfonyl)amide;
at 40 ℃;
for 48h;
Reagent/catalyst;
Temperature;
Catalytic behavior;
|
97%
|
|
In
toluene;
for 2h;
Reflux;
|
96%
|
|
With
N-methylmorpholinium propanesulfonic acid ammonium hydrogensulfate;
at 25 ℃;
for 0.05h;
chemoselective reaction;
Inert atmosphere;
neat (no solvent);
|
95%
|
|
With
zirconium phosphate;
In
neat (no solvent);
at 60 ℃;
for 1h;
Green chemistry;
|
95%
|
|
With
(2,3,4,5,6-pentafluorophenyl)ammonium triflate;
In
neat (no solvent);
at 20 ℃;
for 0.666667h;
|
95%
|
|
Sulfate; tin(IV) oxide;
at 20 ℃;
for 0.333333h;
|
94%
|
|
With
nickel zirconium phosphate;
In
neat (no solvent);
at 40 ℃;
for 0.25h;
|
93%
|
|
sulfuric acid;
for 1h;
Heating;
|
92%
|
|
With
Cu(2+)*Zr(4+)*2PO4(3-) = CuZr(PO4)2;
at 60 ℃;
for 0.5h;
|
92%
|
|
With
iron zirconium phosphate;
In
neat (no solvent);
at 40 ℃;
for 0.25h;
Green chemistry;
|
91%
|
|
Montmorillonite KSF;
for 3.5h;
Ambient temperature;
|
90%
|
|
With
Montmorillonite KSF;
for 3.5h;
Ambient temperature;
|
90%
|
|
With
phosphorus pentoxide; silica gel;
at 20 ℃;
for 0.333333h;
|
90%
|
|
With
multi-walled carbonnanotubes functionalized with phosphonic acid;
In
neat (no solvent);
at 20 ℃;
for 1.33333h;
|
85%
|
|
With
sodium hydroxide;
|
75%
|
|
With
sulfuric acid;
|
|
|
With
sodium hydroxide;
|
|
|
With
sodium acetate;
|
|
|
With
pyridine;
|
|
|
chloromethyl polystyrene supported gadolinium triflate;
In
dimethyl sulfoxide;
at 20 ℃;
for 0.5h;
|
99 % Chromat.
|
|
With
sulfuric acid;
|
|
|
With
1-butyl-3-methylimidazolium 4-methylbenzenenesulfonate; 1-butyl-3-methylimidazolium Tetrafluoroborate;
at 50 ℃;
for 0.666667h;
|
95 %Chromat.
|
|
With
iron(III) phosphate;
at 20 ℃;
for 11h;
chemoselective reaction;
|
92 %Chromat.
|
|
With
5,10,15,20-tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate;
In
acetonitrile;
at 20 ℃;
for 0.0333333h;
|
98 %Chromat.
|
|
With
C13H16NO6S2(1+)*HO4S(1-);
at 25 ℃;
for 0.116667h;
Green chemistry;
|
97 %Chromat.
|
|
With
triethylamine;
In
dichloromethane;
at 20 ℃;
for 12h;
|
|
|
With
pyridine;
at 100 ℃;
|
|
|
With
potassium carbonate;
In
dichloromethane;
at 20 ℃;
for 24h;
|
|
|
at 150 ℃;
for 3h;
|
|
|
With
sulfuric acid;
at 20 ℃;
for 0.5h;
|
533-18-6 Upstream products
-
127-09-3
sodium acetate
-
108-24-7
acetic anhydride
-
95-48-7
ortho-cresol
-
64-19-7
acetic acid
533-18-6 Downstream products
-
704-65-4
2-(bromomethyl)phenyl acetate
-
876-02-8
4-hydroxy-3-methylphenyl methyl ketone
-
699-91-2
2-acetyl-6-methylphenol
-
855354-81-3
acetic acid-(4-iodo-2-methyl-phenyl ester)
